Introduction to Ambient Air Pollution



Air pollution can be classified as a chemical, particulate matter, or biological agent that modifies the natural characteristics of the atmosphere. The atmosphere is a complex, dynamic natural gaseous system that is essential to support life on planet Earth. Ambient air pollution has long been recognized as a threat to human health as well as to the Earth's ecosystems.

Fairbanks Ice Fog
Ice fog over Fairbanks, Alaska in winter 2005. Temperature approximately minus 30F. Joseph N. Hall


There are many substances in the air which may impair the health of plants and animals (including humans), or reduce visibility. These arise both from natural processes and human activity. Substances not naturally found in the air or at greater concentrations or in different locations from usual are referred to as pollutants.

Pollutants can be classified as either primary or secondary. Usually, primary pollutants are substances directly emitted from a process, such as ash from a volcanic eruption, the carbon monoxide gas from a motor vehicle exhaust or sulfur doixide released from factories.

Factory Pollution


Secondary pollutants are not emitted directly. Rather, they form in the air when primary pollutants react or interact. An important example of a secondary pollutant is ground level ozone - one of the many secondary pollutants that make up photochemical smog.

Some pollutants may be both primary and secondary: that is, they are both emitted directly and formed from other primary pollutants. Major primary pollutants produced by human activity include:

  • Sulfur oxides (SOx) especially sulfur dioxide are emitted from burning of coal and oil.
  • Nitrogen oxides (NOx) especially nitrogen dioxide are emitted from high temperature combustion. Can be seen as the brown haze dome above or plume downwind of cities.
  • Carbon monoxide is a product created by incomplete combustion of fuel such as natural gas, coal or wood. Vehicular exhaust is a major source of carbon monoxide.
  • Carbon dioxide (CO2), a greenhouse gas emitted from combustion.
  • Volatile organic compounds (VOCs), such as hydrocarbon fuel vapors and solvents.
  • Particulate matter (PM), measured as smoke and dust. PM10 is the fraction of suspended particles 10 micrometers in diameter and smaller that will enter the nasal cavity. PM2.5 has a maximum particle size of 2.5 µm and will enter the bronchial tubes and lungs.
  • Toxic metals, such as lead, cadmium and copper.
  • Chlorofluorocarbons (CFCs), harmful to the ozone layer emitted from products currently banned from use.
  • Ammonia (NH3) emitted from agricultural processes.
  • Odors, such as from garbage, sewage, and industrial processes
  • Radioactive pollutants produced by nuclear explosions, war explosives, and natural processes such as the radioactive decay of radon.

    Secondary pollutants include:

  • Particulate matter formed from gaseous primary pollutants and compounds in photochemical smog, such as nitrogen dioxide.
  • Ground level ozone (Smog) (O3) formed from NOx and VOCs.
  • Peroxyacetyl nitrate (PAN) similarly formed from NOx and VOCs.

    Worldwide air pollution is responsible for large numbers of deaths and cases of respiratory disease. While major stationary sources are often identified with air pollution, the greatest source of emissions is actually mobile sources, mainly automobiles.

    There are several sources of ambient or outdoor air pollution which will be discussed further. Some of these sources are:

  • Stationary Sources - smoke stacks of power plants, manufacturing facilities, municipal waste incinerators
  • Mobile Sources - motor vehicles, aircraft etc.
  • Combustion-fired power plants
  • Controlled burn practices used in agriculture and forestry management
  • Motor vehicles generating air pollution emission
  • Marine vessels, such as container ships or cruise ships, and related port air pollution
  • Burning wood, fireplaces, stoves, furnaces and incinerators and wildfires
  • Oil refining, power plant operation and industrial activity in general
  • Fumes from paint, hair spray, varnish, aerosol sprays and other solvents.
  • Waste deposition in landfills, which generate methane
  • Military uses, such as nuclear weapons, toxic gases, germ warfare and rocketry
  • Dust from natural sources, usually large areas of land with little or no vegetation
  • Methane, emitted by the digestion of food by animals, for example cattle
  • Volcanic activity, which produce sulfur, chlorine, and ash particulates.

    Factory Pollution


    Some environmental issues from ambient air pollution are the greenhouse effect and ocean acidification The greenhouse effect is a phenomenon whereby greenhouse gases create a condition in the upper atmosphere causing a trapping of heat and leading to increased surface and lower tropospheric temperatures. Greenhouse gases include methane, hydrofluorocarbons, perfluorocarbons, chlorofluorocarbons, NOx, and ozone. Many greenhouse gases, contain carbon, and some of that from fossil fuels.

    Ocean acidification is the name given to the ongoing decrease in the pH of the Earth's oceans, caused by their uptake of anthropogenic carbon dioxide from the atmosphere. Between 1751 and 1994 surface ocean pH is estimated to have decreased from approximately 8.179 to 8.104 (a change of -0.075).

    Factory Pollution

    http://www.pacificscience.org/tfoceanacidification.html.


    While the full ecological consequences of these changes in calcification are still uncertain, it appears likely that many calcifying species will be adversely affected. There is also a suggestion that a decline in the coccolithophores (single cell algae and phytoplankton) may have secondary effects on climate change, by decreasing the earth's albedo via their effects on oceanic cloud cover.

    Aside from calcification, organisms may suffer other adverse effects, either directly as reproductive or physiological effects (e.g. CO2-induced acidification of body fluids, known as hypercapnia), or indirectly through negative impacts on food resources. However, as with calcification, as yet there is not a full understanding of these processes in marine organisms or ecosystems. http://www.tasmedia.org/node/1214.

    Another document Impacts of ocean acidification on Coral Reefs and other Marine Calcifiers can be found at: http://www.ucar.edu/communications/Final_acidification.pdf.



    When I was in school I hated science. I couldn't understand it. Not only was it in another language [English], but all the examples were foreign. If we begin to speak of 'Yup'ik science,' we will give our children something they can understand. --Agatha John-Shields, Bethel, March 2004